Solubility and thermodynamic properties of sodium theophylline salt in aqueous sodium hydroxide solution at different temperatures
نویسندگان
چکیده
The solubility data of sodium theophylline salt in the water and aqueous hydroxide systems with molarities 0.00, 0.01, 0.10, 0.20, 0.49, 0.96 mol kg −1 at temperatures ranging from 283.15 to 368.15 K are determined via equilibrium method. experimental results show that increases on increasing temperature same concentration NaOH solution decreases an increase temperature. These correlate well polynomial empirical equation, modified Apelblat λh equation. At time, it is found equation gives better correlation than equations. three models theophylline. Van’t Hoff used estimate thermodynamic properties including dissolution enthalpy, entropy, Gibbs free energy change when dissolved different concentrations. obtained experiments can provide basic for cooling crystallization, separation, purification expected be great significance research development caffeine production.
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ژورنال
عنوان ژورنال: Journal of chemical research
سال: 2023
ISSN: ['1747-5198', '2047-6507']
DOI: https://doi.org/10.1177/17475198231166563